Removing Hard Drive

Having had no end of problems connecting to my 4tb WD MyCloud since upgrading to El Capitan

Have you updated to 10.11.1?

Pulling the MyCloud apart is almost certainly a warranty violation…

An alternative approach may be to connect a USB drive to the port, then access via SSH (using a device other than your Mac, perhaps?), and copying the user shares to the mounted USB drive. You’d need to have a modicum of Linux experience to find the mounted USB drive, and know where the user shares are (actually, they’re just under ‘/shares’; pretty simple, really…). The point of this method is that everything is done by the MyCloud, and doesn’t use the Mac.