Backing up anew External Drive

I recently added another external drive (G-Drive) for data storage on my PC but my WD MyBook is not backing up files on that drive.  Any help on how to fix that?

Smartware doesn’t backup most external drives, only the internal ones. Try with another software =)

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Can you recommend another software?

I use Windows Backup (7 Ultimate, 32-bit). But GoodSync is very good.

I use GoodSync and it’s very good. I sync to 2 extrnals and on a third I do system images with Acronis TI.