It may be that the drive is severely fragmented. I’m not sure if the NAS OS tries to address this, if it is the case. However, (hypothetical) defrag can’t take place on a really full drive. You might try backing up moderate sized blocks of data, and then deleting them from the RED drive to free up space.
Is this drive in a NAS enclosure on a network connection, or in a directly connected situation? In either case, does it have a history of painfully slow transfers, or is this new behavior? If networked, is there anything else on the network you can compare it to, like a broadband internet connection, another drive or computer? If it is being used internally or otherwise directly connected, clearing space (~15-20% free) should allow you to defrag it, assuming that fragmentation is a contributing factor.
If the drive is in PIO mode and won’t change to DMA, you can try going to the Driver tab and uninstalling the driver. The system should then reinstall it if you go to the Action menu and select “Scan for Hardware Changes”