Sync Content From A Network Shared Folder

I was hoping to find out if i am able to set up a sync for more than one shared folder on my network; currently I have my media seperated on 2 different drives :I and :J.  I am always updating the the movies I have on both drives but with the way the sync works atm (not sure how to change it) it will only syc with one or the other.

Cheers in advance

D

What if you include both shares under a same location?