See (or move your post to) the dedicated subforum for the PR4100 where users more familiar with that device may be able to assist with your question/issue.
You likely have to configure the new drives that have been added to the My Cloud using the My Cloud Dashboard > Storage tab. The older OS3 PR4100 User Manual has a chapter on the Storage tab: https://products.wdc.com/library/UM/ENG/4779-705142.pdf#page=59
The following WD Knowledgebase article may be relevant.