Check out Silverstone’s HDDBoost:
http://www.silverstonetek.com/product.php?pid=245&area=
Also, the Z68 chipset now supports SSD caching:
http://www.tomshardware.com/reviews/z68-express-lucidlogix-virtu-ssd-caching,2888.html
And, I believe Seagate’s Momentus XT already does exactly what you’ve described
(but, I don’t know if it’s OK to mention Seagate products here; Moderator, please advise):
http://www.seagate.com/www/en-us/products/laptops/laptop-hdd
Hope this helps.
MRFS