Reformating to fat32

You can run any number of Linux “Live” distros…

As long as you can boot from something like a USB or DVD-ROM, you can make a bootable media and boot into a Linux distro directly, and perhaps format the disk from there.

For example, the Fedora distro:    http://fedoraproject.org/en/get-fedora

  – has instructions for booting from a USB stick or CD/DVD ROM

Same with Ubuntu:   http://www.ubuntu.com/download

Neither image will do anything to your existing OS, so long as you don’t actually try to INSTALL the live media.